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catalyst-free 1

dynamic transesterification reaction 1

high mechanical properties 1

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Rosin side chain type catalyst-free vitrimers with high cross-link density, mechanical strength, and

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 9,   Pages 1267-1279 doi: 10.1007/s11705-022-2291-7

Abstract: Rosin, a natural product, is an ideal raw material for the preparation of polymers in a more sustainableIn this study, hydrogenated rosin was adopted for preparing hydrogenated rosin side-chain type diacids, which were reacted with mixed epoxy to obtain rosin side-chain type vitrimers.Moreover, our work expanded the application field of rosin, increased the added value of rosin, and provideda novel method for preparing rosin-based vitrimers with ideal properties.

Keywords: vitrimers     rosin     catalyst-free     high mechanical properties     dynamic transesterification reaction    

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Rosin side chain type catalyst-free vitrimers with high cross-link density, mechanical strength, and

Journal Article